| Polyurethanes
or Urethanes are a family of elastomers, similar
to rubbers, offering a unique combination of properties. When
designing these products, it is important to note that these
properties and some of the terminology differ considerably
from metals or plastics. Elastomers are extensible and deform
easily, and some properties change as the part is stressed.
The combination of many outstanding properties within the
single material makes a urethane distinctive from conventional
rubbers and plastics. Urethane elastomers are often considered
as a bridge between rubbers and structural plastics because
they combine many of the desirable properties of both.
Poly-Pro
Polyurethanes are thermosetting materials
characterized by unusual toughness. They combine resilience
and high load-bearing capacity with resistance to impact,
abrasion and compression set and degradation by oxygen, ozone
and oil. They are liquid polymers which are mixed with curing
agents and poured into molds of any cross section or size
to produce parts with consistent properties throughout. Since
it is a low pressure molding process, large and inexpensive
molds are often fabricated with sheet metal, aluminum, urethane
or wood.
Our Polyurethanes
are available from 20A (soft as gum rubber) to 75D (hard as
a bowling ball).
Compounding and processing methods and conditions have a major
bearing on the performance of a given product. A myriad of
compounds can be produced in the same hardness, using a variety
of chemical backbones. Even a minor variation in the ratios
of the chemicals can result in a major variation in performance
of that product for a particular application. Knowing a particular
application, the molder can vary his compound to optimize
some of the properties. Proper application engineering is
very important for the success of a product. The physical
properties listed are for the standard compounds designed
for our common applications. These are not to be construed
as a warranty for any particular application. Application
of sound Engineering principles and practices should be used.
Caveat emptor…buyer
beware: All urethanes are not created equal. Unlike
thermoplastics, a thermoset urethane is ‘created’
by the molder. Not all urethanes are created equal. The type
of polymer and the type and ratio of curative play a very
crucial role in the performance of the product. A urethane
molded product can be compounded in a garage by using very
minimal equipment (a paint mixer stick, a can, an oven and
a scale is all that is needed to be a molder. They can get
a bit more sophisticated and use an electric drill for mixing.
The investment will still be in 3 digits !). Because of this,
there are lots of companies that call themselves Urethane
molders. But the performance and consistency of their products
will be debatable as compared to some molders that use sophisticated
metering and mixing machinery.
Types of Polyurethanes:
Cast Polyurethanes based on TDI, MDI,PPDI, polyethers, polyesters
and polycaprolactones as building blocks, offer a wide variety
of application possibilities and advantages.
Polyethers perform well
in dynamic applications and in hydrolytic environments.
They have better dynamic properties. They are extensively
used in applications such as die-forming pads, press brake
dies, die springs, fork lift tires, roller coaster wheels,
rolls for steel and paper mills.
Polyesters have superior
cut, tear and abrasion resistance as well as better resistance
to oil and solvents. Typical applications include hydraulic
seals, scraper blades, rolls for graphic arts, pipeline pigs,
chute liners, etc.
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